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The nicotine from the cigarettes also mimics your bodys anxiety response, which makes you feel more anxious after smoking

Other harmful chemicals such as nitrosamines and nitrosonornicotine were present in the electronic cigarette aerosol but again at much lower levels - the nitrosamine content in cigarettes is about 380 times that found in e-cigarette aerosol, and the nitrosonornicotine level is around 40 times higher in cigarette smoke

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Baker RR, Coburn S, Liu C, Tetteh J (2005) Pyrolysis of saccharide tobacco ingredients: a TGA-FTIR investigation