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45 The second step is an irreversible rate-limiting reaction catalyzed by branched-chain -keto acid dehydrogenase (BCKDH), which is phosphorylated and inactivated by the specific kinase BCKDH kinase (BCKDK) and dephosphorylated and activated by Protein phosphatase 1 K (PPM1K)

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Glycation isotopic labeling with 13C-reducing sugars for quantitative analysis of glycated proteins in human plasma

J Allergy Clin Immunol 117:836841 Hoyer A, Rehbinder EM, Frdig M, Asad S, Ldrup Carlsen K, Endre KMA, Granum B, Haugen G, Hedlin G, Monceyron Jonassen C (2022) Filaggrin mutations in relation to skin barrier and atopic dermatitis in early infancy

doi: 10.1016/s1350-9462(02)00059-9