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In this paper, we consider the (mis)uses of aqueous p K a values in the organic curriculum and their pedagogical effects, argue for the adoption of p K a values measured in an organic solvent (DMSO) in organic textbooks and reference materials, and explore the thermodynamic origin of the effect of solvent on acidity

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[DOI] [PubMed] [Google Scholar] Hartl D, Starosta V, Maler K, Beck-Speler I, Rebhan C, Becker BF, Latzin P, Fischer R, Ratjen F, Huber RM, Rietschel E, Krass-Etschmann S, Greise M