As the identified di-, hexa- and decadepsipeptides are not in line with the proposed biosynthetic assembly of three ready-made tetradepsipeptides 8,9 , these findings prompted us to ask whether the candidate depsipeptide esters are released from chemically unstable NRPS-bound PCP- S -ester or TE- O -ester intermediates of cereulide biosynthesis upon transesterification with ethanol, or are formed as artifacts by esterification of free depsipeptides or as cereulide degradation products released upon ethanolysis
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Sevoflurane offers protection to the glycocalyx, with patients in the sevoflurane group exhibiting significantly reduced concentrations of glycocalyx markers in the blood (such as SDC-1, HS, and HA) and enzymes responsible for glycocalyx degradation (such as MMP-9 and cathepsin-B), compared to the control drug propofol [128]
