2: (100g27.6mg) No
-Dioxygenases, two of which exist (in tobacco and Arabidopsis ) and are distinct from the lipoxygenases (and related structurally to mammalian COX enzymes), work in concert with caleosins, i.e., Ca 2+ binding proteins associated with lipid bodies, to generate various 2 R hydroperoxy fatty acids and then the hydroxide, e.g., 2hydroxy-linolenic acid (illustrated)
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As both side chains are on the same side of the 3 R ,7 S -cyclopentanone ring and the keto group at C-6 can tautomerize to an enol, the more thermodynamically stable (3 R ,7 R )-isomer (-)- or trans -jasmonic acid is usually isolated (90% of the equilibrium mixture) during analysis